Episode 1 - It's Dejiko-nyo!

Dejiko (Digi Charat), Puchiko (Petit Charat) and Gema are heading for Earth in their cat shaped UFO, in order to complete Dejiko's "princess training", but because of an explosion, Puchiko is blown outside the ship.

Episode 2 - Together With Puchiko-nyo?

After they manage to land safely on Earth, Dejiko and Gema search for Puchiko and find her inside a toy department.

Episode 3 - The Riddle Cell Phone-nyo

Dejiko is trying to find her white, cat-face shaped pochette, in which she had her cellphone.

Episode 4 - I Won't Call You Rabi~En~Rose-nyo

Dejiko and Puchiko meet a junior high girl, Usada Hikaru, that insists to be called Rabi-en-Rose.

Episode 5 - Baked Puchiko is Delicious-nyu

Dejiko and Puchiko become popular after making cakes called "Puchikos" that look just like Puchiko's pochette.

Episode 6 - Dejiko is a Princess-nyo

Gema tells everybody about how life was on Planet Di Gi Charat, the home planet of Dejiko and Puchiko.

Episode 7 - A Splendid Day for Usada-nyo

Rabi-en-Rose wants to enter an idol competition.

Episode 8 - A Public Bath Called "Daily Hot Water"-nyo

Because of a new green bath toy that grows when wet is occupying the bathroom, Dejiko and the others decide to go to a public bath.

Episode 9 - Usada's Bo-Bo School -nyo!

At school, Hikaru notices that Kyoshi has forgotten his lunch at home, and tries to get a "date" with him, offering him to share her lunch. However, Digiko and Puchiko are on their way to school bringing Kyoshi his lunch.

Episode 10 - Nazo no Omise ni Otsukai nyo

Digiko, Puchiko and Genma go shopping and end up inside a weird store where the cashier is a man with a jack o'lantern for a head.

Episode 11 - Ayatori Meijinsen nyo

Puchiko leaves on a quest to find some "nattou" (fermented soybeans), while Gema and Daifuku confront each other in an "ayatori" (string tricks) contest.

Episode 12 - Amaenbou da nyo

A young boy called Amaenbou who loves sweets and pulling on Digiko's tail starts following Digiko and Puchiko around everywhere they go.

Episode 13 - Shoutengai de Oouridashi nyo

At a special town meeting, it is decided that they should ask Akari Usada to have a concert there. The entire Neko Maneki Shopping Center prepares for the celebration.

Episode 14 - Oouridashi de Kayou Show nyo

On the day of the big celebration, Digiko and Puchiko try to get inside Akari's trailer, to talk to their idol.

Episode 15 - Itokono Neechan ka nyo

Rabi en Rose tells a story about how she and Akari were friends a long time ago before she became an idol.

Episode 16 - Digiko Megane ha Kowai nyo

Everybody in town starts wearing special glasses that makes them look like Digiko, just to annoy her.

Episode 17 - Digiko no Wagashizukuri nyo

When Daifuku and Kinako leave on vacation, Digiko is left in charge of the bakery and has to make a cake for a client.

Episode 18 - Kiyoshi, You're Great-nyo!

Kiyoshi starts developing super powers and accidentally destroys the school.

Episode 19 - Derorin Chirorin nyo

Episode 20 - Himashiyu kara waita nyo

Episode 21 - Manmaru Jinja no ikimono nyo

Digiko and Puchiko follow Hikaru to a shrine to see what she's doing. There they meet her best friend, Majingabbo, a water demon.

Episode 22 - Kowai Picnic nyo

Digiko and the others go on a picnic, but they get lost in the forest and meet a giant who wants to eat them.

Episode 23 - Shoutengai ni terebi ga kita nyo

A documentary about the Neko Maneki Shopping Center is being filmed, and Digiko and the others are cast as actors.

Episode 24 - Puchiko ranking happyou nyu

Digiko and the others hold a party for Puchiko, where they ask her to name her favorite persons.

Episode 25 - Princess shugyou ha ii choushi nyo

Episode 26 - Are You Homesick-nyo?

Episode 27 - Rabi-en tanjou no Himitsu

Episode 28 - Mekara Beam wo dasanai nyo

Episode 29 - Akihabara ni Otsukai nyo

Episode 30 - Korega Manatsu no Akihabara nyo

Episode 31 - Linna? Daredesitaka nyo

Episode 32 - Linna Nemurimakuri nyo

Episode 33 - Natsumatsuri ga yattekuru nyo

Episode 34 - Iyoiyo Natsumatsuri nyo

Episode 35 - Kowai Hanashi nyo

Episode 36 - Ujaja kan no Yuurei-chan nyo

Episode 37 - Aqua-chan ga Tsureta nyo

Episode 38 - Umi de Koi no Natsu! Sugu-n Gema

Episode 39 - Digiko, Eiga ni Shutsuen suru nyo

Episode 40 - Akari to Kyouen suru nyo

Episode 41 - Sashisuseso ga Umareta nyo

Episode 42 - Digiko Furima ni Chousen nyo

Episode 43 - Digiko wo Mamoru Knight da nyo

Episode 44 - Kaasama ga kita nyo

Episode 45 - Uchuujin Shuurai nyo

Episode 46 - Puchiko Shiawase wo Sagasu nyu

Episode 47 - Mike to Deka zakana Arawareta nyo

Episode 48 - Densetsu no Sao ga Hoshii nyo

Episode 49 - Kinoko gari ha Tanoshii nyo

Episode 50 - Omochan ga Nakunaru nyo

Episode 51 - Magikano Misuteki Tour nyo

Episode 52 - Digiko Kaeru nyo

Episode 53 - Piyoko ha Aku no Shuryou nyo

Episode 54 - Ryakushite Bugedan nyo

Episode 55 - Kareida-san ga Kuru nyo

Episode 56 - Kareida-san pinch nyo

Episode 57 - Dejiko is Number One-nyo!

Episode 58 - Mekara Beam ha Akogare nyu

Episode 59 - Nanikaya de arubaito nyo

Episode 60 - Yasushi tai Riku nazo no taiketsu nyo

Episode 61 - Shouwakusei ga Gekitotsu nyo!

Episode 62 - Digiko no Warashibe chouja nyo

Episode 63 - Gosenzo-sama ga yattekita nyo

Episode 64 - Digiko kira kira nyo

Episode 65 - Bugedan Puchiko wo Nerau nyo

Episode 66 - Bugedan Usada wo Naerau nyo

Episode 67 - Piyoko no Gokuaku Item nyo

Episode 68 - DiGi Charat to ha nandesuka

Episode 69 - Kiyoshi wo Sagasu nyo

Episode 70 - Warui Yokan ni goshoutai nyo

Episode 71 - Fushigi no Kuni no Usamimi-chan

Episode 72 - Digiko mo Usamimi Hoshii nyo

Episode 73 - Nenmatsu Akihabara ni Iku nyo

Episode 74 - Akihabara 7 nin Musume nyo

Episode 75 - Shoutengai mo Christmas nyo

Episode 76 - Santa-san no Otetudai nyo

Episode 77 - Let's Find the Golden Door -nyo!

Episode 78 - Can We Really Find the Golden Door -nyo?

Episode 79 - The Princess School -nyo!

Episode 80 - Usada, the Bo-Bo Princess -nyo!

Episode 81 - Kyuushoku ha Uresii nyo

Episode 82 - Puri Puri Bu- Kessei yo

Episode 83 - Kagai Jugyou ni Odekake nyo

Episode 84 - Princess kun Toujousa!

Episode 85 - The Costumes Store -nyo!

Episode 86 - I Need to Act as a Princess -nyo!

Episode 87 - An Elegant Lesson -nyo!

Episode 88 - The Princesses' Music Group is Born -nyo!

Episode 89 - Rod P Shishakai Akihabara nyo

Episode 90 - Kuma King Ge Dan Akihabara nyo

Episode 91 - Valentine no Choco wo Mamoru nyo

Episode 92 - Fushigi-kun ni Arigato nyo

Episode 93 - Akari no Shigotoba ni iku nyo

Episode 94 - Yukiyama de Yahhohho- nyo

Episode 95 - Princess Tenkousei ga Kuru nyo

Episode 96 - Me kara Beam ha Oshimaika nyo?

Episode 97 - Kaeri Michi de Yori Michi nyo

Episode 98 - Digiko no Karei na Tabi nyo

Episode 99 - Princess School Seven Wonders-nyo

Episode 100 - Shoutengai ni Princess School nyo

Episode 101 - Chotto dake Oneesan kibun nyo

Episode 102 - Digiko no Sakubun Happyou nyo

Episode 103 - Princess School Festival-nyo

Episode 104 - Di Gi Charat Returns to the Planet-nyo